oxidation of hantzsch 1,4- dihydropyridines to pyridines with thallium triacetate
نویسندگان
چکیده
hantzsch 1, 4-dihydropyridines (1,4-dhps) can be oxidized to the corresponding pyridine derivatives by thallium triacetate in high yields.
منابع مشابه
Oxidation of Hantzsch 1,4- Dihydropyridines to Pyridines with Thallium Triacetate
Hantzsch 1, 4-dihydropyridines (1,4-DHPs) can be oxidized to the corresponding pyridine derivatives by thallium triacetate in high yields.
متن کاملAROMATIZATION OF HANTZSCH 1,4- DIHYDROPYRIDINES WITH ZINC CHLOROCHROMATE NONAHYDRATE
Hantzsch 1 ,4- dihy&opyridines are rapidly oxidized to the corresponding pyridine derivatives using zinc chlorochromate nonahydrate [Zn(C1CrO ) .9H O] in dichloromethane at room temperature. In addition to aromatization, no loss of the 4- substituent is observed
متن کامل“On-Water” Catalyst-Free Ecofriendly Synthesis of the Hantzsch Dihydropyridines
An eco-friendly "on-water" protocol for efficient catalyst-free synthesis of the Hantzsch dihydropyridines from aryl, heteroaryl, alkyl, and vinylogous aldehydes has been developed with minimum auxiliary substances, toxic reagents, organic solvents, and disposal problems.
متن کاملSodium Hypochlorite-Dowex 1X8-200: A Convenient Oxidizing Reagant
The polymer supported hypochlorite ion is a facile selective oxidizing agent for the oxidation of various alcohols to aldehydes and ketones. Similarly is successfully oxidizes various Hantzsch type 1,4- dihydropyridines to corresponding pyridines.
متن کاملaromatization of hantzsch 1,4- dihydropyridines with zinc chlorochromate nonahydrate
hantzsch 1 ,4- dihy&opyridines; are rapidly oxidized to the corresponding pyridine derivatives using zinc chlorochromate nonahydrate [zn(c1cro ) .9h o] in dichloromethane at room temperature. in addition to aromatization, no loss of the 4- substituent is observed
متن کاملN,N'-ethylene-bis(benzoylacetoniminato) copper (II), Cu(C22H22N2O2), a new reagent for aromatization of Hantzsch 1,4-dihydropyridines.
A variety of Hantzsch 1,4-dihydropyridines were oxidized to their corresponding pyridines in high yields in the presence of Cu(C22H22N2O2) in refluxing acetic acid.
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عنوان ژورنال:
iranian journal of chemistry and chemical engineering (ijcce)ناشر: iranian institute of research and development in chemical industries (irdci)-acecr
ISSN 1021-9986
دوره 22
شماره 2 2003
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